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Abstract The baryonic physics shaping galaxy formation and evolution are complex, spanning a vast range of scales and making them challenging to model. Cosmological simulations rely on subgrid models that produce significantly different predictions. Understanding how models of stellar and active galactic nucleus (AGN) feedback affect baryon behavior across different halo masses and redshifts is essential. Using the SIMBA and IllustrisTNG suites from the Cosmology and Astrophysics with MachinE Learning Simulations (CAMELS) project, we explore the effect of parameters governing the subgrid implementation of stellar and AGN feedback. We find that while IllustrisTNG shows higher cumulative feedback energy across all halos, SIMBA demonstrates a greater spread of baryons, quantified by the closure radius and circumgalactic medium (CGM) gas fraction. This suggests that feedback in SIMBA couples more effectively to baryons and drives them more efficiently within the host halo. There is evidence that the different feedback modes are highly interrelated in these subgrid models. The parameters controlling the stellar feedback efficiency significantly impact AGN feedback, as seen in the suppression of black hole mass growth and delayed activation of AGN feedback to higher-mass halos with increasing stellar feedback efficiency in both simulations. Additionally, the AGN feedback efficiency parameters affect the CGM gas fraction at low halo masses in SIMBA, hinting at complex, nonlinear interactions between the AGN and supernova feedback modes. Overall, we demonstrate that stellar and AGN feedback are intimately interwoven, especially at low redshift, due to subgrid implementation, resulting in halo property effects that might initially seem counterintuitive. 

Abstract Most diffuse baryons, including the circumgalactic medium (CGM) surrounding galaxies and the intergalactic medium (IGM) in the cosmic web, remain unmeasured and unconstrained. Fast radio bursts (FRBs) offer an unparalleled method to measure the electron dispersion measures (DMs) of ionized baryons. Their distribution can resolve the missing baryon problem and constrain the history of feedback theorized to impart significant energy to the CGM and IGM. We analyze the Cosmology and Astrophysics with Machine Learning Simulations using three suites, IllustrisTNG, SIMBA, and Astrid, each varying six parameters (two cosmological and four astrophysical feedback), for a total of 183 distinct simulation models. We find significantly different predictions between the fiducial models of the suites owing to their different implementations of feedback. SIMBA exhibits the strongest feedback, leading to the smoothest distribution of baryons and reducing the sight-line-to-sight-line variance in DMs betweenz= 0 and 1. Astrid has the weakest feedback and the largest variance. We calculate FRB CGM measurements as a function of galaxy impact parameter, with SIMBA showing the weakest DMs due to aggressive active galactic nucleus (AGN) feedback and Astrid the strongest. Within each suite, the largest differences are due to varying AGN feedback. IllustrisTNG shows the most sensitivity to supernova feedback, but this is due to the change in the AGN feedback strengths, demonstrating that black holes, not stars, are most capable of redistributing baryons in the IGM and CGM. We compare our statistics directly to recent observations, paving the way for the use of FRBs to constrain the physics of galaxy formation and evolution. 

Through a combination of many analytical approaches, we show that a metal organic nanotube (UMON) displays selectivity for H 2 O over all types of heavy water (D 2 O, HDO, HTO). Water adsorption experiments combined with vibrational and radiochemical analyses reveal significant differences in uptake and suggest that surface adsorption processes may be a key driver in water uptake for this material.